1. Occurrence of rare earth elements and classification of minerals

Occurrence of the rare earth element in the earth's crust are the following three: (1) participate in the mineral crystal, constituting the essential mineral components, forming an independent minerals (e.g., monazite, bastnaesite), which is a rare earth element in the crust The main form of occurrence in (2) is dispersed in rock-forming minerals and other rare minerals in the form of isomorphic substitutions (calcium, strontium , barium, manganese, etc.), which is a secondary form of occurrence; 3) Adsorption in the form of ions on other mineral surfaces or between particles, which is a rare form of occurrence.

According to the chemical composition of rare earth minerals, the rare earth minerals that have been discovered can be classified into nine categories, and various typical rare earth minerals are listed in Table 1.

Table 1 Classification of rare earth minerals

category

Main mineral

Fluoride

Yttrium fluorite, calcium fluoride, sodium stone yttrium, cerium ore fluoro

Carbonate, fluorocarbonate

Bastnasite, yellow river mine, barium carbonate mine, etc.

Phosphate

Monazite, xenotime

Silicate

Gadolinite, scandium, yttrium stone

Oxide

Fergusonite ore, aeschynite, dilute black gold ore

Arsenate

Arsenic ore

Borate

Mink calcium borax

Sulfate

Fluorine hydrate

Citrate

Antimony ore

Second, the main industrial minerals and their physical and chemical properties

At present, there are about 250 kinds of rare earth-containing minerals found in the world, and there are about 50 to 60 kinds of rare earth minerals with research and utilization value. There are only 10 kinds of rare earth minerals with industrial exploitation and practical value. The physical and chemical properties of rare earth minerals are listed in Table 2.

Table 2 Physical and chemical properties of rare earth minerals

Mineral name

Chemical properties

Molecular formula

REO%

Soluble

Bastnasite

CeCO 3 F

74.77

Soluble in HCl

Monazite

CePO 4

67.76

H 2 SO 4 , HCl, H 3 PO 4 are slightly soluble in NaOH

Phosphonium ore

YPO 4

63.23

Soluble in H 2 SO 4 , H 3 PO 4 slightly soluble in NaOH

Fluorocarbon calcium strontium ore

Ce 2 Ca(CO 3 ) 3 F 2

60.30

Soluble in HCl, H 2 SO 4 , HNO 3

Silicon germanium ore

Y 2 FeBe(SiO 4 ) 2 O 2

51.51

Soluble in HCl, slightly soluble in NaOH

Easy stone

(CeThY)(TiNb) 2 O 6

29.36

Soluble in H 2 SO 4 , H 3 PO 4 soluble in HF,

H 2 SO 4 +(NH 4 ) 2 SO 4

Niobium perovskite Ce

(NaCeCa)(TiNb)O 3

28.71

Insoluble in HCl, H 2 SO 4 , HNO 3 soluble in HF

Complex gold mine

Y(TiNB) 2 (O·OH) 4

29.28~33.43

Soluble in H 2 SO 4 , H 3 PO 4 , HF

Black gold mine

Y(TiNbTi) 2 (O·OH) 6

20.82~29.93

Soluble in HF, H 2 SO 4 , H 3 PO 4

Brown sugar mine

YNbO 4

39.94

Soluble in H 2 SO 4 , HNO 3

(Continued Table 2)

Mineral name

Physical properties

Density g∕cm 2

hardness

Specific magnetic susceptibility × 10 -6 cm 3 ∕g

Dielectric constant

Crystal form

2 fluorocarbon antimony ore

4.72~5.12

4 to 5.2

12.59~10.19

5.65~6.96

Trigonal system

Monazite

4.83~5.42

5 to 5.5

12.75~10.58

4.45~6.69

Monoclinic system

Phosphonium ore

4.4~4.8

4~5

31.28~26.07

8.1

Orthogonal system

Fluorocarbon calcium strontium ore

4.2 to 4.5

4.2 to 4.6

14.37~11.56

Trigonal system

Silicon germanium ore

4.0 to 4.65

6.5~7

62.5~49.38

Monoclinic system

Easy stone

5~6.4

4.5 to 6.5

18.04~12.92

4.4~4.8

Orthorhombic system

Barium perovskite

4.58~4.89

5.8~6.3

6.54~5.23

5.56~7.8

Isometric crystal system

Complex gold mine

4.28~5.05

4.5 to 5.5

21.05~18.00

Orthorhombic system

Black gold mine

4.2~5.87

5.5 to 6.5

27.38~18.41

3.7~5.29

Orthorhombic system

Brown sugar mine

4.89~5.82

5.5 to 6.5

29.2~21.16

4.5~16

Tetragonal system

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